Unstable Intermediates in the Gaseous Phase: The Thermal Decomposition of Alkyl Sulfides RSnR
β Scribed by Prof. Dr. Hans Bock; Dipl.-Chem. Shamsher Mohmand
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 192 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The cyclic sulfenic ester 1,2βoxathiolane (**1**) decomposes thermally (400 β 450 K) exclusively to give acrolein (**3**) __via__ 3βmercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2βoxathiolaneβthietane 1βoxide equilibrium
Here, K is a constant which depends only on the disk dimensions, the diffusivity of dissolved gas, and the liquid viscosity and density. N is the number of disks over which an appreciable amount of gas has not yet penetrated into the rejuvenation depth.