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Unstable Intermediates in the Gaseous Phase: The Thermal Decomposition of Acyl Chlorides RCOCI

โœ Scribed by Prof. Dr. Hans Bock; Dr. Takakuni Hirabayashi; Dipl.-Chem. Shamsher Mohmand; Dr. Bahman Solouki


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
280 KB
Volume
16
Category
Article
ISSN
0044-8249

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๐Ÿ“œ SIMILAR VOLUMES


Thermal Decomposition of 1,2-Oxathiolane
โœ Carlsen, Lars ;Egsgaard, Helge ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 293 KB ๐Ÿ‘ 1 views

## Abstract The cyclic sulfenic ester 1,2โ€oxathiolane (**1**) decomposes thermally (400 โ€“ 450 K) exclusively to give acrolein (**3**) __via__ 3โ€mercaptopropanal (**2**) by loss of hydrogen sulfide. Isotopic labelling experiments reveal the presence of a 1,2โ€oxathiolaneโ€thietane 1โ€oxide equilibrium