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Unsaturated Thiacrown Ethers: Synthesis, Physical Properties, and Formation of a Silver Complex

✍ Scribed by Tsuchiya, Takahiro; Shimizu, Toshio; Kamigata, Nobumasa


Book ID
127019509
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
110 KB
Volume
123
Category
Article
ISSN
0002-7863

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Synthesis, structure, and complexation b
✍ Toshio Shimizu; Satoru Komatsuzaki; Kazunori Hirabayashi πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 177 KB

## Abstract Partially unsaturated 14‐ and 28‐membered thiacrown ethers, **3** and **4**, which possess alternating Z‐carbon‐‐carbon double bonds and propylene chains, were synthesized by stepwise reactions. The crystal structure of larger cyclic compound **4** was determined by X‐ray crystallograph