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Unsaturated Selenacrown Ethers: Synthesis, Structure, and Formation of Silver Complexes

✍ Scribed by Shimizu, Toshio; Kawaguchi, Mari; Tsuchiya, Takahiro; Hirabayashi, Kazunori; Kamigata, Nobumasa


Book ID
121433742
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
378 KB
Volume
70
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Synthesis, structure, and complexation b
✍ Toshio Shimizu; Satoru Komatsuzaki; Kazunori Hirabayashi πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 177 KB

## Abstract Partially unsaturated 14‐ and 28‐membered thiacrown ethers, **3** and **4**, which possess alternating Z‐carbon‐‐carbon double bonds and propylene chains, were synthesized by stepwise reactions. The crystal structure of larger cyclic compound **4** was determined by X‐ray crystallograph

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The bis-monodentate ligands 1 and 2 based on the interconnection of two pyrazolyl units by CH 2 (CH 2 OCH 2 ) n CH 2 (n=3 or 4) spacers, respectively, lead to the formation of either mono nuclear silver metallamacrocycle 10 in the case of 1 or binuclear silver metallamacrocycle 11 in the case of 2.