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Unsaturated heterocyclic systems. XLII. Pyrolysis of azabullvalenes and 7-azabicyclo[4.2.2]deca-2,4,7,9-tetraenes

✍ Scribed by Paquette, Leo A.; Krow, Grant R.; Malpass, John R.; Barton, Thomas J.

Book ID
127236612
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
228 KB
Volume
90
Category
Article
ISSN
0002-7863

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Thermal isomerization of bicyclo[4.2.2]d
Thermal isomerization of bicyclo[4.2.2]deca-2,4,7,9-tetraene
✍ Maitland Jones Jr.; Billy Fairless πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 176 KB

CENTRAL to the consideration of mechanism in many of the transformations of molecules of the formula (CH),, has been tetracyclo[4.4.0.02"0 .05"]deca-3,8-diene (I).3a-g We describe here a degenerate isomerization of bicyclo-[4.?.2]deca-2,4,7,9-tetraene (II) which most strongly implicates I as an inte