𝔖 Bobbio Scriptorium
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Unsaturated acids and macrocyclic lactones. Communication 10. Synthesis of the lactone of 3-hydroxy-2,4,6-trimethylheptanedioic acid

✍ Scribed by L. D. Bergel'son; S. G. Batrakov


Book ID
112421136
Publisher
Springer
Year
1963
Tongue
English
Weight
629 KB
Volume
12
Category
Article
ISSN
1573-9171

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Hypervalent iodine oxidation of 5-keto a
✍ R.M. Moriarty; R.K. Vaid; T.E. Hopkins; B.K. Vaid; O. Prakash† πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 203 KB

Hypervalent iodine oxidation of 5-ketoacids, using [hydroxy(tosyloxy)iodo]benzene in dichloromethane under refluxing conditions yielded keto-y-lactones. Oxidation of 4,6-diketoacids with [hydroxy(tosyloxy)iodolbenzene at room temperature afforded the corresponding diketo-&lactones.