Unprecedented Sulfone-Functionalized Metal–Organic Frameworks and Gas-Sorption Properties
✍ Scribed by Eleftheria Neofotistou; Christos D. Malliakas; Pantelis N. Trikalitis
- Book ID
- 102795187
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 678 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Gas storage: A new, sulfone‐functionalized dicarboxylate‐based ligand (see figure) is capable of directing the formation of novel metal–organic frameworks with unprecedented organic and inorganic secondary building units. A high CO~2~ uptake with remarkable selectivity over CH~4~, N~2~, and H~2~ was observed at near‐ambient temperature.magnified image
📜 SIMILAR VOLUMES
Gas sorption isotherm measurements performed on the evacuated derivatives of four porous metalorganic frameworks ), and Zn 4 O(BDC) 3 ‚(DMF) 8 C 6 H 5 Cl (MOF-5), reveal type I isotherms for n ) 2, 3, and 5, which is evidence of microporous and accessible channels having high structural integrity a