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Unprecedented Sulfone-Functionalized Metal–Organic Frameworks and Gas-Sorption Properties

✍ Scribed by Eleftheria Neofotistou; Christos D. Malliakas; Pantelis N. Trikalitis


Book ID
102795187
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
678 KB
Volume
15
Category
Article
ISSN
0947-6539

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✦ Synopsis


Abstract

Gas storage: A new, sulfone‐functionalized dicarboxylate‐based ligand (see figure) is capable of directing the formation of novel metal–organic frameworks with unprecedented organic and inorganic secondary building units. A high CO~2~ uptake with remarkable selectivity over CH~4~, N~2~, and H~2~ was observed at near‐ambient temperature.magnified image


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Gas sorption isotherm measurements performed on the evacuated derivatives of four porous metalorganic frameworks ), and Zn 4 O(BDC) 3 ‚(DMF) 8 C 6 H 5 Cl (MOF-5), reveal type I isotherms for n ) 2, 3, and 5, which is evidence of microporous and accessible channels having high structural integrity a