Infinite Metal-Carboxylate Nanotube Constructed Metal-Organic Frameworks and Gas Sorption Properties
✍ Scribed by Lv, Xiaoxia; Tang, Sifu; Li, Liangjun; Cai, Jinjun; Wang, Chao; Xu, Xianrui; Zhao, Xuebo
- Book ID
- 121194708
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 831 KB
- Volume
- 2013
- Category
- Article
- ISSN
- 1434-1948
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## Abstract **Gas storage**: A new, sulfone‐functionalized dicarboxylate‐based ligand (see figure) is capable of directing the formation of novel metal–organic frameworks with unprecedented organic and inorganic secondary building units. A high CO~2~ uptake with remarkable selectivity over CH~4~, N
Gas sorption isotherm measurements performed on the evacuated derivatives of four porous metalorganic frameworks ), and Zn 4 O(BDC) 3 ‚(DMF) 8 C 6 H 5 Cl (MOF-5), reveal type I isotherms for n ) 2, 3, and 5, which is evidence of microporous and accessible channels having high structural integrity a