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Unique Guest-Inclusion Properties of a Breathing Ionic Crystal of K3[Cr3O(OOCH)6(H2O)3][α-SiW12O40]⋅16 H2O

✍ Scribed by Sayaka Uchida; Noritaka Mizuno


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
238 KB
Volume
9
Category
Article
ISSN
0947-6539

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The preparation of complex 1 . ~~4 and its crystal structure analysis have both been reported [S.Xl. The synthesis of the N-methylated nickel chelates roc-5.6 will be reported at a later date. In contrast to ruc-4[8], rw-5,6 are 1101 oxygen-sensitive. ## Cation Inclusion within the Mixed-Valence