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Unimolecular rectification down to 105 K and spectroscopy of hexadecylquinolinium tricyanoquinodimethanide

✍ Scribed by Robert M. Metzger

Book ID
117543571
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
158 KB
Volume
109
Category
Article
ISSN
0379-6779

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πŸ“œ SIMILAR VOLUMES

Demonstration of unimolecular electrical
Demonstration of unimolecular electrical rectification in hexadecylquinolinium tricyanoquinodimethanide
✍ Robert M. Metzger πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 348 KB

Asymmetries in the macroscopic and the nanoscopic DC electrical conductivity through Langmuir-Blodgett multilayers and monolayers of g g g g g-(n-hexadecyl)quinolinium tricyanoquinodimethanide (HDQ-3CNQ, 1) are due to a transition from the ground-state zwitterion to a probably neutral excited-state

Hexadecylquinolinium tricyanoquinodimeth
Hexadecylquinolinium tricyanoquinodimethanide, a unimolecular rectifier between 370 and 105 K and its spectroscopic properties
✍ Robert M. Metzger πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 142 KB

A single molecule, g-hexadecyl-quinolinium tricyanoquinomethanide, 1, whose ground state is zwitterionic: D + -p-A -, with dipole moment 4328 Debyes, and whose first excited state is undissociated: D 0 -p-A 0 , with an estimated moment between 3 and 9 Debyes, is a unimolecular rectifier of electrica