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Rectification between 370 and 105 K in Hexadecylquinolinium Tricyanoquinodimethanide

โœ Scribed by Chen, Bo; Metzger, Robert M.


Book ID
127079206
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
88 KB
Volume
103
Category
Article
ISSN
0022-3654

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๐Ÿ“œ SIMILAR VOLUMES


Hexadecylquinolinium tricyanoquinodimeth
โœ Robert M. Metzger ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 142 KB

A single molecule, g-hexadecyl-quinolinium tricyanoquinomethanide, 1, whose ground state is zwitterionic: D + -p-A -, with dipole moment 4328 Debyes, and whose first excited state is undissociated: D 0 -p-A 0 , with an estimated moment between 3 and 9 Debyes, is a unimolecular rectifier of electrica

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Asymmetries in the macroscopic and the nanoscopic DC electrical conductivity through Langmuir-Blodgett multilayers and monolayers of g g g g g-(n-hexadecyl)quinolinium tricyanoquinodimethanide (HDQ-3CNQ, 1) are due to a transition from the ground-state zwitterion to a probably neutral excited-state