Unimolecular photodissociation of s-tetrazine and derivatives
β Scribed by Windisch, V. L.; Smith, A. B.; Hochstrasser, R. M.
- Book ID
- 121428954
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 582 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0022-3654
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Ultraviolet (266 nm) and wsible (532 nm) photodissociauon of colhsion-free s-tetraziie show asymmetric dynamics with production of one tmnshtiondIy cool and one translationally hot HCN molecule. Furthermore. visiile and ultraviolet dynamics are nearly identical, argumg that two-photon excitation IS
## Abstract Tetrazineβbased organic species are interesting intermediates for organic synthesis and represent a source of new materials bearing specific properties with potential applications in biology and material science. ^1^H, ^13^C, ^15^N NMR measurements carried out in solution and in the sol