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Unexpected Substituent Effects in Face-to-Face π-Stacking Interactions

✍ Scribed by Sinnokrot, Mutasem Omar; Sherrill, C. David


Book ID
111690987
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
88 KB
Volume
107
Category
Article
ISSN
1089-5639

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Chemical double mutant cycles have been used to measure the magnitude of edge-to-face aromatic interactions in hydrogen-bonded zipper complexes as a function of substituents on both aromatic rings. The interaction energies vary depending on the combination of substituents from +1.0 kJ mol-1 (repulsi