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Origin of substituent effects in edge-to-face aryl–aryl interactions

✍ Scribed by Wheeler, Steven E.; Houk, K.N.

Book ID
115535535
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
808 KB
Volume
107
Category
Article
ISSN
0026-8976

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Chemical double mutant cycles have been used to measure the magnitude of edge-to-face aromatic interactions in hydrogen-bonded zipper complexes as a function of substituents on both aromatic rings. The interaction energies vary depending on the combination of substituents from +1.0 kJ mol-1 (repulsi