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Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine

✍ Scribed by Alexander V. Artem’ev; Svetlana F. Malysheva; Boris G. Sukhov; Nataliya A. Belogorlova; Yurii V. Gatilov; Victor I. Mamatyuk; Nina K. Gusarova


Book ID
113798719
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
400 KB
Volume
22
Category
Article
ISSN
0959-9436

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Reaction of primary phosphines with elem
✍ Alexander V. Artem’ev; Nina K. Gusarova; Svetlana F. Malysheva; Victor I. Mamaty 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 338 KB

Primary phosphines readily react with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs) in the molar ratio 1:3:2 under mild conditions (70 °C, 0.5 h, ethanol) to afford alkali metal trithiophosphonates in good to high yields (72-90%).