✦ LIBER ✦
Reaction of primary phosphines with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs): a novel and facile three-component synthesis of trithiophosphonates
✍ Scribed by Alexander V. Artem’ev; Nina K. Gusarova; Svetlana F. Malysheva; Victor I. Mamatyuk; Yurii V. Gatilov; Boris A. Trofimov
- Book ID
- 104098632
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- French
- Weight
- 338 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Primary phosphines readily react with elemental sulfur and alkali metal hydroxides (MOH, M = Na, K, Cs) in the molar ratio 1:3:2 under mild conditions (70 °C, 0.5 h, ethanol) to afford alkali metal trithiophosphonates in good to high yields (72-90%).