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Unexpected reactivity of oxygenated 2-acyl-1,3-dithianes with electrophiles

✍ Scribed by Michael Smietana; Alain Valleix; Charles Mioskowski

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 208 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02561-3

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✦ Synopsis

Lithium enolates of oxygenated acyl-dithiane undergo unexpected regiospecific reactions with electrophiles. Reaction of aldehydes with oxygenated acyl-dithiane leads to the formation of the corresponding monosubstituted b-hydroxy-acyl-dithiane.

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