Electrophilic Reactivities of 1,2-Diaza-
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Dipl.-Chem. Tanja Kanzian; Dr. Simona Nicolini; Dr. Lucia Deβ
Crescentini; Prof.β
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Article
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2010
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John Wiley and Sons
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English
β 417 KB
π 1 views
## Abstract The kinetics of the reactions of 1,2βdiazaβ1,3βdienes **1** with acceptorβsubstituted carbanions **2** have been studied at 20βΒ°C. The reactions follow a secondβorder rate law, and can be described by the linear free energy relationship logβ__k__(20βΒ°C)=__s__(__N__+__E__) [Eq.β (1)]. Wit