𝔖 Bobbio Scriptorium
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Unexpected formation of thioacridone and its spectral properties

✍ Scribed by André Deleenheer; Y. Y. Shum; J. E. Sinsheimer; J. H. Burckhalter

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
228 KB
Volume
60
Category
Article
ISSN
0022-3549

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✦ Synopsis

17a-(2-Dimethylaminoethyl)-17a-aza-D-homo-5androsten -3/3 -01 (XIVbMethod D-Compound X (2.0 9.) was dissolved in 30 ml. of dioxane, a solution of 1.0 g. of lithium aluminum hydride in 300 ml. of dioxane was added, and the mixture was refluxed for 48 hr. Excess hydride was destroyed with water. The inorganic salts were filtered and washed with dioxane. The dioxane solution was evaporated to dryness, and the residue was crystallized from ethanol to give 1.8 g. (94%) of white crystals of XIV,. The hydrobromide salt of XIV was prepared by passing HBr gas into its acetone solution and crystallizing from ethanol to give white needles, m.p. 309-310".

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