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Unexpected Formation of Ruthenium(II) Hydrides from a Reactive Dianiline Precursor and 1,2-(Ph 2 P) 2 -1,2 -closo -C 2 B 10 H 10

✍ Scribed by Adams, Jeramie J.; Del Negro, Andrew S.; Arulsamy, Navamoney; Sullivan, B. Patrick


Book ID
126225987
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
307 KB
Volume
47
Category
Article
ISSN
0020-1669

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Cage opening of 1,2-(CH2OH)2-closo-1,2-C
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## Abstract The reaction of 1,2‐(CH~2~OH)~2~‐__closo__‐1,2‐C~2~B~10~ H~10~ carborane with 2‐(aminomethyl)‐pyridine in methylene chloride at room temperature led to the partial cage degradation of the __closo__ carborane and its conversion to the __nido__ derivative. The addition of cobalt chloride