A Spirocyclic Borate and a Dihydroborate Derived from the 1,2-Diselenolato-1,2-dicarba-closo-dodecaborane(12) Dianion [1,2-(1,2-C2B10H10)Se2]2–: Structures, NMR Spectroscopy, and DFT Calculations
✍ Scribed by Bernd Wrackmeyer; Elena V. Klimkina; Wolfgang Milius
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 569 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The reaction of 1,2‐(CH~2~OH)~2~‐__closo__‐1,2‐C~2~B~10~ H~10~ carborane with 2‐(aminomethyl)‐pyridine in methylene chloride at room temperature led to the partial cage degradation of the __closo__ carborane and its conversion to the __nido__ derivative. The addition of cobalt chloride
The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat