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Unexpected formation of 5,5-diethoxy-5H-1,2,3-dithiazoles from 5H-1,2,3-dithiazole-5-thiones

โœ Scribed by Oleg I. Bol'shakov; Lidia S. Konstantinova; Rinat R. Aysin; Natalia V. Obruchnikova; Elena D. Lubuzh; Oleg A. Rakitin


Book ID
108209761
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
229 KB
Volume
20
Category
Article
ISSN
0959-9436

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โœ Hyi-Seung Lee; Kyongtae Kim ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

-vlidene derivatives 1-3 with primary and secovdary alkylarmnes in CH,CL at room temperature gave 2,5-dzhydro-2-iminopyrroles (22-55%) and 2, 5-dihydro-2-imino[urans (18-62%). However, similar treatment of alltyl (4-chloro-5H-1,2,3dithtazol-5-ylidene)cyanoacetates under the same conditions gave (Z)-