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Ring transformation of (4-chloro-5H-1,2,3-dithiazol-5-ylidene)acetonitriles to 3-haloisothiazole-5-carbonitriles

โœ Scribed by Kalogirou, Andreas S.; Christoforou, Irene C.; Ioannidou, Heraklidia A.; Manos, Manolis J.; Koutentis, Panayiotis A.


Book ID
121469144
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
706 KB
Volume
4
Category
Article
ISSN
2046-2069

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โœ Hyi-Seung Lee; Kyongtae Kim ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

-vlidene derivatives 1-3 with primary and secovdary alkylarmnes in CH,CL at room temperature gave 2,5-dzhydro-2-iminopyrroles (22-55%) and 2, 5-dihydro-2-imino[urans (18-62%). However, similar treatment of alltyl (4-chloro-5H-1,2,3dithtazol-5-ylidene)cyanoacetates under the same conditions gave (Z)-