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Unexpected Chemoselective Debromination and Reduction of 1,1-Dibromo-1-alkenes Mediated by Samarium Metal in Methanol.

โœ Scribed by Lei Wang; Pinhua Li; Yuanyuan Xie; Yanbin Ding


Book ID
101947862
Publisher
John Wiley and Sons
Year
2003
Weight
104 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The reduction of different 2โ€azolylโ€and azinylisoquinolinium salts with sodium borohydride in methanol was studied. Surprisingly, contrary to what is found in the literature 1,2โ€dihydroisoquinoline derivatives were obtained. Their formation was attributed to the electron withdrawing cha