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Unexpected CC Bond Formation and Synthesis of Tetranuclear Zinc Carbodiimide Clusters from the Reaction of ZnMe2 and iPrNCNiPr

✍ Scribed by Marlene Münch; Ulrich Flörke; Michael Bolte; Stephan Schulz; Dietrich Gudat

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 384 KB
Volume: 47
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200704417

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✍ Prof. Dr. Achim Müller; Dipl.-Chem. Uta Reinsch 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 236 KB

In the IR spectrum (solid, Nujol) the bands of greatest intensity (with exception of the HZO bands) lie at 2118 [vaS(CN -E)], ]; the bands in the v(CN) region indicate high symmetry of the anion (2)