Activation and Sulfur-Atom Transfer Reaction of Cluster-Bonded S-Bridge Ligands: Synthesis of the New Cluster [MoS4(CN)9]5− from [MoS(S2)6]2− and CN−

✍ Scribed by Prof. Dr. Achim Müller; Dipl.-Chem. Uta Reinsch

• Publisher: John Wiley and Sons
• Year: 1980
• Tongue: English
• Weight: 236 KB
• Volume: 19
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198000721

✦ Synopsis

In the IR spectrum (solid, Nujol) the bands of greatest intensity (with exception of the HZO bands) lie at 2118 [vaS(CN -E)], ]; the bands in the v(CN) region indicate high symmetry of the anion (2)