Unexpected Catalyzed CC Bond Cleavage by Molecular Oxygen Promoted by a Thiyl Radical †
✍ Scribed by Baucherel, Xavier; Uziel, Jacques; Jugé, Sylvain
- Book ID
- 120202828
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 93 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph~3~P)~3~RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds __via__ CC‐bond cleavage. For example, 2,3‐dimethyl‐2‐butene was transformed into acetone. Butadiene and isoprene also undergo oxidative C
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