𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rhodium-Catalyzed C,C-Double Bond Cleavage by Molecular Oxygen

✍ Scribed by Helmut Bönnemann; Washington Nunez; Dieter M. M. Rohe

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
328 KB
Volume
66
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph~3~P)~3~RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds via CC‐bond cleavage. For example, 2,3‐dimethyl‐2‐butene was transformed into acetone. Butadiene and isoprene also undergo oxidative CC‐bond cleavage to form acrylaldehyde and related compounds.

📜 SIMILAR VOLUMES

Lactone Formation by Rhodium-Catalyzed C
Lactone Formation by Rhodium-Catalyzed C−C Bond Cleavage of Cyclobutanone
✍ Masahiro Murakami; Takuo Tsuruta; Yoshihiko Ito 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB 👁 1 views

Of the variety of synthetic transformations mediated by transition metals, catalytic processes involving cleavage of C À C single bonds are among the most difficult to achieve. [1] Hence, their development remains an important challenge in organic chemistry. We recently found that the bond between t

ChemInform Abstract: Rhodium-Catalyzed C
ChemInform Abstract: Rhodium-Catalyzed C—C Bond Cleavage Reactions
✍ David Necas; Martin Kotora 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 15 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Gold(I)-Catalyzed Oxidative Cleavage of
Gold(I)-Catalyzed Oxidative Cleavage of a C—C Double Bond in Water.
✍ Dong Xing; Bingtao Guan; Guixin Cai; Zhao Fang; Liping Yang; Zhangjie Shi 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 23 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.