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Unexpected Addition of Methyl 3,3,3-Trifluoropyruvate to “Push-Pull” Enamines Having a Methyl Group at α-Position.

✍ Scribed by Dmitriy M. Volochnyuk; Aleksandr N. Kostyuk; Dmitriy A. Sibgatulin; Aleksandr E. Petrenko


Publisher
John Wiley and Sons
Year
2005
Weight
19 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of Novel Octahydro-1,5-imino-3-benzazocin-4,7,10-trione Derivatives Having a Methyl Group at the C-2 Position as ABC Ring Models of Saframycins. -Simple and efficient syntheses of (Z)-3-benzylidenepiperazinedione ( VII) in both racemic and optically active forms are described. Compound (V