Unexpected Splitting of ansa-Ytterboacen
✍
Igor L. Fedushkin; Tatyana V. Petrovskaya; Mikhail N. Bochkarev; Sebastian Deche
📂
Article
📅
2001
🏛
John Wiley and Sons
🌐
English
⚖ 107 KB
👁 1 views
Recently we reported on the synthesis of the C 2 -symmetric trans-rac-ansa-lanthanoacenes [1] [(h 5 -C 12 H 8 ) 2 M(thf) 2 ] (M Yb, 1; Sm, 2) by reductive coupling of acenaphthylene (acene) with activated metallic ytterbium or samarium. [2] The acenyl radical anions formed in the course of these red