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Unerwartete Spaltung von Ansa-Ytterbo- und Ansa-Calcoacen: Bildung von [(η2-C12H8)ZrCl2(thf)3] und (Me3Si)2C12H8

✍ Scribed by Igor L. Fedushkin; Tatyana V. Petrovskaya; Mikhail N. Bochkarev; Sebastian Dechert; Herbert Schumann


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
105 KB
Volume
113
Category
Article
ISSN
0044-8249

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Unexpected Splitting of ansa-Ytterboacen
✍ Igor L. Fedushkin; Tatyana V. Petrovskaya; Mikhail N. Bochkarev; Sebastian Deche 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 1 views

Recently we reported on the synthesis of the C 2 -symmetric trans-rac-ansa-lanthanoacenes [1] [(h 5 -C 12 H 8 ) 2 M(thf) 2 ] (M Yb, 1; Sm, 2) by reductive coupling of acenaphthylene (acene) with activated metallic ytterbium or samarium. [2] The acenyl radical anions formed in the course of these red