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under high pressure

✍ Scribed by Wang, Hai-Yan; Chen, Xiang-Rong; Zhu, Wen-Jun; Cheng, Yan


Book ID
118057496
Publisher
The American Physical Society
Year
2005
Tongue
English
Weight
67 KB
Volume
72
Category
Article
ISSN
1098-0121

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Cleavage of tert-butyldiphenylsilyl (TBDPS) ether was examined under high pressure conditions (1.0 GPa) using HF/pyridine in DMF. This method proved to be exceptionally suitable for deprotecting the TBDPS group that resides at the sterically hindered position. Under these conditions, various types o