Uncontrolled pseudoliving free-radical polymerization of methyl methacrylate in the presence of butyl-p-benzoquinones
✍ Scribed by V. A. Dodonov; Yu. L. Kuznetsova; A. I. Vilkova; A. S. Skuchilina; V. I. Nevodchikov; L. N. Beloded
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 306 KB
- Volume
- 56
- Category
- Article
- ISSN
- 1573-9171
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Detailed kinetic analysis of AIBN-initiated polymerization of methylmethacrylate in presence of p-benzoquinone has been reported. Primary radical transfer, whereby a primary radical transfers its radical reactivity to a transfer agent, has been considered along with macroradical transfer. It is foun
## Abstract **Summary:** Experimental and modeling studies of addition–fragmentation chain transfer (AFCT) during radical polymerization of methyl methacrylate in the presence of poly(methyl methacrylate) macromonomer with 2‐carbomethoxy‐2‐propenyl __ω__‐ends (PMMA‐CO~2~Me) at 60 °C are reported. T
We carried out the radical polymerization of methyl methacrylate (MMA) at 0 -80°C in the presence of magnesium bromide. The polymerization rate and the molecular weight of the resulting polymers increased according to the amount of the added magnesium bromide as the Lewis acid. It was revealed that