Controlled radical polymerization of methyl methacrylate in the presence of 2-bromoethanol
✍ Scribed by Shinji Sugihara; Akmal Hadi Ma’ Radzi; Shinya Hori; Isao Ikeda
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 268 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0170-0839
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## Abstract **Summary:** Plasma‐initiated controlled/living radical polymerization of methyl methacrylate (MMA) was carried out in the presence of 2‐cyanoprop‐2‐yl 1‐dithionaphthalate. Well‐defined poly(methyl methacrylate) (PMMA), with a narrow polydispersity, could be synthesized. The polymerizat
## Abstract We report first results on the controlled radical polymerization of 2,3‐epithiopropyl methacrylate (ETMA) also known as thiiran‐2‐ylmethyl methacrylate. Reversible addition‐fragmentation chain transfer (RAFT) of ETMA was carried out in bulk and in solution, using AIBN as initiator and t