Mechanism of the controlled radical polymerization of styrene and methyl methacrylate in the presence of dicyclopentadienyltitanium dichloride
โ Scribed by Dmitry F. Grishin; Stanislav K. Ignatov; Alexander A. Shchepalov; Alexey G. Razuvaev
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 153 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.631
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Radical polymerizations of styrene in the presence of C 60 have been conducted at 90ยฐC in benzene using benzoyl peroxide (BPO) as initiator. The behaviors of C 60 are investigated by monitoring BPO concentration, C 60 content, and polymerization time. It is found that C 60 acts like a radical absorb
The effect of fullerene (C 60 ) on the radical polymerization of methyl methacrylate (MMA) in benzene was studied kinetically and by means of ESR, where dimethyl 2,2ะ-azobis(isobutyrate) (MAIB) was used as initiator. The polymerization rate (R p ) and the molecular weight of resulting poly(MMA) decr