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Uncommon Ferromagnetic Interactions in a Homometallic Co(II) Chain Bridged by a Single End-to-End Azide

✍ Scribed by Yoo, Houng Sik; Kim, Jae Il; Yang, Namgeun; Koh, Eui Kwan; Park, Je-Geun; Hong, Chang Seop

Book ID: 120933662
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 105 KB
Volume: 46
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic7014995

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with