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“Umpolung” von Bor im [B(CN)4]− Anion durch Reduktion zum Dianion [B(CN)3]2−

✍ Scribed by Priv.-Doz. Dr. Eduard Bernhardt; Vera Bernhardt-Pitchougina; Prof. Dr. Helge Willner; Dr. Nikolai Ignatiev

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 348 KB
Volume: 123
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.201105848

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“Umpolung” at Boron by Reduction of [B(C

“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−

✍ Priv.-Doz. Dr. Eduard Bernhardt; Vera Bernhardt-Pitchougina; Prof. Dr. Helge Wil 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB 👁 1 views

which, for example, convert protons into hydridic hydrogen atoms in BÀH bonds, are well-investigated. For instance, nucleophilic boron in metal borides (e.g., MgB