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“Umpolung” at Boron by Reduction of [B(CN)4]− and Formation of the Dianion [B(CN)3]2−

✍ Scribed by Priv.-Doz. Dr. Eduard Bernhardt; Vera Bernhardt-Pitchougina; Prof. Dr. Helge Willner; Dr. Nikolai Ignatiev

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
332 KB
Volume
50
Category
Article
ISSN
0044-8249

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✦ Synopsis

which, for example, convert protons into hydridic hydrogen atoms in BÀH bonds, are well-investigated. For instance, nucleophilic boron in metal borides (e.g., MgB

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The structure, binding energies, harmonic vibrational frequencies, and nuclear quadrupole coupling constants of the cyanodihydroborate and boron tricyanide Ž . known compounds, but no structural experimental data available complexes with ammonia were calculated using the Møller᎐Plesset perturbation