Umlagerungsreaktionen von Metallodiphosphapropenen des Typs (η5-C5Me5)(CO)2FeP(SiMe3) — P = C(R)(SiMe3) (R = SiMe3, Ph)
✍ Scribed by Weber, Lothar ;Kirchhoff, Ralf ;Boese, Roland
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1993
- Tongue
- English
- Weight
- 617 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0009-2940
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📜 SIMILAR VOLUMES
## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C
Professor Gerhard Fritz zum 80. Geburtstag gewidmet Inhaltsu È bersicht. Bei der Reaktion a È quimolarer Mengen an [(g 5 -C 5 Me 5 )(CO) 2 RuSb(SiMe 3 ) 2 ] (1 b) mit Carbonsa È urechloriden RC(O)Cl (R = tBu, Ph, 1-Adamantyl) werden die Acyl(trimethylsilyl)stibanido-Komplexe [(g 5 -C 5 Me 5 ) (CO) 2