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Umlagerungen von 1-Methyl-Δ1-3-keto-steroiden zu 1-Methylen-steroiden

✍ Scribed by Rudolf Wiechert; Ulrich Kerb; Paul-Eberhard Schulze


Book ID
104854171
Publisher
Springer
Year
1964
Tongue
English
Weight
298 KB
Volume
51
Category
Article
ISSN
0028-1042

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Umlagerung von 3-Thioxo-Δ1,4-steroiden,
✍ Möller, Stephanie ;Weiß, Dieter ;Beckert, Rainer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 313 KB

Rearrangement of 3‐Thioxo‐Δ^1,4^‐steroids, a New Approach of Steroid Thiols 3‐Thioxoandrosta‐1,4‐dien‐17‐one (1) is subjected to a dienthion‐thiophenol rearrangement in aprotic and protic solvents in the presence of an acid catalyst resulting in the formation of 1‐(acetylthio)‐4‐methylestra‐1,3,5(1