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Ultrasound-Promoted Oxidation of Sulfides with Hydrogen Peroxide under Catalyst-Free Conditions

โœ Scribed by Khatri, Praveen K.; Jain, Suman L.; Sain, Bir


Book ID
118012941
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
254 KB
Volume
50
Category
Article
ISSN
0888-5885

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TMSCl-promoted selective oxidation of su
โœ Kiumars Bahrami; Mohammad M. Khodaei; Behrooz H. Yousefi; Mehdi Sheikh Arabi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 584 KB

Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.