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TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide

✍ Scribed by Kiumars Bahrami; Mohammad M. Khodaei; Behrooz H. Yousefi; Mehdi Sheikh Arabi

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
584 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.

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