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Cerium (IV) triflate-catalyzed selective oxidation of sulfides to sulfoxides with aqueous hydrogen peroxide

โœ Scribed by B. Rama Raju; S. Sarkar; U. Chandramoulali Reddy; Anil K. Saikia


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
225 KB
Volume
308
Category
Article
ISSN
1381-1169

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TMSCl-promoted selective oxidation of su
โœ Kiumars Bahrami; Mohammad M. Khodaei; Behrooz H. Yousefi; Mehdi Sheikh Arabi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 584 KB

Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.