Ueber Nitrobutan
✍ Scribed by Demole, Eugen
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1874
- Weight
- 234 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0365-9631
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📜 SIMILAR VOLUMES
The equilibrium constant for the keto-enol tautomerism of 3nitrobutan-2-one K T = [enol]/[ketone] has been measured in water as 4.57 ϫ 10 -3 (pK T = 2.34) by combining the rate constants for ketonisation of the enolate form and pK a of the ketone at 25 °C. The rates of ketonisation were measured by
Using a relative rate method, rate constants for the gas-phase reactions of the OH radical with 1-and 2-propyl nitrate, 1-and 2-butyl nitrate and l-nitrobutane have been determined in the presence of one atmosphere of air at 298 t 2 K. Using rate constants for the reactions of the OH radical with pr