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Télomérisation de l'isobutylène

✍ Scribed by Taha, Mohammed ;Rigal, Gérard ;Piétrasanta, Yves ;Platzer, Nicole ;Sudres, Pierre ;Raynal, Serge

Publisher
Wiley (John Wiley & Sons)
Year
1981
Weight
475 KB
Volume
182
Category
Article
ISSN
0025-116X

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✦ Synopsis

Abstract

The telomerization of isobutene was investigated using redox catalysis, free radical, and particularly cationic initiation. The influence of the initiator on the degree of polymerization and the structure of the telomers was studied. Redox and free radical telomerization with CCl~4~ and CCl~3~Br were found to permit synthesis and identification of the monoadduct structure. Cationic telomerization gives regular structure compounds and the molecular weights are higher than those obtained by other methods of telomerization.

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