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Types of interaction of meso-tetraphenylporphyrin with alkali and alkaline-earth metal ions

✍ Scribed by Tandrima Chaudhuri; Manas Banerjee; Ayan Ghosh; Animesh Pan; Soumya Ganguly Neogi

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
842 KB
Volume
26
Category
Article
ISSN
1522-7235

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## Abstract Compound [(dph‐BIAN)Mg(THF)]~2~ (**2**) was prepared by reacting magnesium metal with 1,2‐bis[(2‐biphenyl)imino]acenaphthene (dph‐BIAN) in THF, followed by crystallization from toluene. Reaction of CaI~2~ with (dpp‐BIAN)Li~2~ in toluene afforded [(dpp‐BIAN)Li]~2~Ca (**3**) (dpp‐BIAN = 1