Two Zn(II) and one Mn(II) complexes using two different hydrazone ligands: spectroscopic studies and structural aspects
β Scribed by Aurkie Ray; Sambuddha Banerjee; Soma Sen; Ray J. Butcher; Georgina M. Rosair; Maria T. Garland; Samiran Mitra
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 668 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1040-0400
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## Abstract Four new mononuclear metal complexes with a mononucleating Schiff base ligand containing two thiadiazoles units have been synthesized. The ligand and metal complexes were characterized by elemental analyses, IR, ^1^H, and ^13^C NMR, UVβvis, ESR, electrospray ionization mass spectra, and
The present work carried out a study on transition metal ion complexes which have been synthesized from 2-acetylpyridine 4 N-(2-pyridyl) thiosemicarbazone (HAPT) 1. These complexes namely [Zn(HAPT)Cl 2 ] 2, [Mn (HAPT)Cl 2 ] 3, [Co (HAPT)Cl 2 ] 4, [Fe(APT)Cl 2 (H 2 O)] 5 and [UO 2 (HAPT)(OAc) 2 ] 6,