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Two-Step Spin Conversion in a Cyanide-Bridged Ferrous Square

✍ Scribed by Masayuki Nihei; Mayumi Ui; Mizuho Yokota; Lingqin Han; Atsushi Maeda; Hideo Kishida; Hiroshi Okamoto; Hiroki Oshio

Book ID: 101568963
Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 260 KB
Volume: 44
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200502216

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✦ Synopsis

Molecules with many spin-crossover sites could be used as multistepped molecular switches. The CNbridged molecular square [Fe II 4 (m-CN) 4 (bpy) 4 (tpa) 4 ](PF 6 ) 4 (bpy = 2,2'bipyridine; tpa = tris(2-pyridylmethyl)amine), a Prussian blue analogue, undergoes thermally induced, two-step spin conversion. For more information, see the Communication by H. Oshio and co-workers on the following pages.

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