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Two-Step Spin Conversion in a Cyanide-Bridged Ferrous Square

โœ Scribed by Masayuki Nihei; Mayumi Ui; Mizuho Yokota; Lingqin Han; Atsushi Maeda; Hideo Kishida; Hiroshi Okamoto; Hiroki Oshio


Book ID
101534972
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
260 KB
Volume
117
Category
Article
ISSN
0044-8249

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Molecules with many spin-crossover sites could be used as multistepped molecular switches. The CNbridged molecular square [Fe II 4 (m-CN) 4 (bpy) 4 (tpa) 4 ](PF 6 ) 4 (bpy = 2,2'bipyridine; tpa = tris(2-pyridylmethyl)amine), a Prussian blue analogue, undergoes thermally induced, two-step spin conver

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## Abstract A dinuclear iron(II) complex containing the new pyridyl bridging ligand, 2,5โ€di(2โ€ฒ,2โ€ฒโ€ฒโ€dipyridylamino)pyridine (ddpp) has been synthesised and characterised by singleโ€crystal Xโ€ray diffraction, magnetic susceptibility and Mรถssbauer spectral methods. This compound, [Fe~2~(ddpp)~2~(NCS)~4