✦ LIBER ✦

Two-step laser excitation fluorescence study of the magnetic field effect on the hydrogen abstraction reaction of anthraquinone in SDS micellar solution

✍ Scribed by Yoshifumi Tanimoto; Katsuko Shimizu; Michiya Itoh

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 252 KB
Volume: 112
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80536-9

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✦ Synopsis

The magnetic field effect on the hydrogen abstraction reaction of anthraquinone in sodium dodecyl sulfate (SDS) micellar solution has been studied by two-step laser escitation fluorescence including a variable delay technique. The risetime of the "cage product" is 380 ns at 0 G and 890 ns at 800 G, while its yield decreases by 20% at 800 G. The results are interpreted in terms of the radical pair model of CIDNP.

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