Two-step enzymatic reaction for the synthesis of pure structured triacylglycerides
โ Scribed by Mohamed M. Soumanou; Uwe T. Bornscheuer; Rolf D. Schmid
- Book ID
- 107496346
- Publisher
- Springer-Verlag
- Year
- 1998
- Tongue
- English
- Weight
- 721 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0003-021X
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## Abstract Enzymatic strategies are reported for the synthesis of (2__R__,3__S__)โ3โaminoโ2โhydroxyโ3โphenylpropionic acid (__ee__ > 98โ%), a key intermediate of the sideโchain of Taxol^ยฎ^, by enzymatic hydrolysis in organic media. The new enzymatic cascade reaction, which took place through __Can
V = 1078.3(5) x lo6 pm3, psalsd = 1.089 g ~m -~, Z = 2, crystal size 0.3 x 0.3 x 0.9 mm3, 173 K, Cu,,, radiation, Enraf-Nonius CAD4, scan width 2.25 <8 < 76.5",4202 symmetry-independent and significant reflections [IF1 >3u(F)] structure solution by direct methods (SHELXS-86 [6]) supplemented by diff